Special theory of relativity in chemistry

Foundations of Chemistry 24 (1):87-95 (2022)
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Abstract

Application of Einstein special theory of relativity in chemistry seems to be superfluous; energies are too low. The average velocity of electron in hydrogen atom is 1/135 c, making its actual mass only 26,6 ppm bigger than the rest mass. However, for heavier elements relativistic effects have to be taken into account and, more, many phenomena cannot be explained without ascribing new mass to electrons, in accordance with Einstein theory. In this paper such phenomena are described: color of metallic gold and Bi and Pb compounds, contraction of Ln-X bond of lanthanide trihalides, voltage of lead-acid and Zn/HgO battery, and the shape of gold clusters. Besides, essentials of Einstein theory and quantum chemistry were problems concerning the validity of Lavoisier law.

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Concepts of space.Max Jammer - 1969 - Cambridge, Mass.,: Harvard University Press.
The ontological autonomy of the chemical world.Olimpia Lombardi & Martín Labarca - 2004 - Foundations of Chemistry 7 (2):125-148.
Just how ab initio is ab initio quantum chemistry?Eric R. Scerri - 2004 - Foundations of Chemistry 6 (1):93-116.

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