A chemical compound in the form of graph terminology is known as a chemical graph. Molecules are usually represented as vertices, while their bonding or interaction is shown by edges in a molecular graph. In this paper, we computed various connectivity indices based on degrees of vertices of a chemical graph of indium phosphide. Afterward, we found the physical measures like entropy and heat of formation of InP. Then, we fitted curves between different indices and the thermodynamical properties, namely, (...) heat of formation and entropy. Curve fitting was done in MATLAB through different methods based on linearity and nonlinearity. Furthermore, we depicted our results numerically and graphically. These numerical systems may give an approach to concentrate on the thermodynamical properties of the compound design of InP at an exceptional level that will help understand the connection between framework measurement and these actions. (shrink)

Similarities in properties among pairs of metallic elements and their compounds in the lower-right quadrant of the Periodic Table have been named the ‘Knight’s Move’ relationship. Here, we have undertaken a systematic study of the only two ‘double-pairs’ of ‘Knight’s Move’ elements within this region: copper-indium/indium-bismuth and zinc-tin/tin-polonium, focussing on: metal melting points; formulas and properties of compounds; and melting points of halides and chalcogenides. On the basis of these comparisons, we conclude that the systematic evidence for ‘Knight’s (...) Move’ relationships derives from similarities in formulas and properties of matching pairs of compounds in the same oxidation state. Physical properties, such as melting points, do not provide consistent patterns and trends and hence should not be considered as a common characteristic of this relationship. (shrink)

Dmitrii Mendeleev’s periodic system is known for its predictive accuracy, but talk of its completeness is rarer. This is surprising because completeness was a quality that Mendeleev saw as important for a systematization of the chemical elements. Here, I explain how Mendeleev’s valuing of completeness influenced the development of his periodic system. After introducing five indicators of its completeness, I zoom into one in particular: Mendeleev’s inclusion of a schematic row of oxides. I then show how it guided Mendeleev’s predictions (...) of indium and ekaboron, which suggests that the valuing of completeness was instrumental for making predictions. (shrink)