Recently, philosophers have come forth with approaches to chemistry based on its actual practice, imparting to it a proper aim and character of its own. These approaches add to the currently growing movement of pluralist philosophies of science. We draw on recent pluralist accounts from chemistry and analyse three notions from modern chemical practice and theory in terms of these accounts, in order to complement the so far more general pluralist approaches with specific evidence. Our survey reveals that the concept (...) of element indicates conceptual pluralisms in chemistry. that electronegativity illustrates methodological pluralism in determining one and the same concept, and that acidity is an instance of plurality hidden behind ‘one notion’. (shrink)

Electronegativity is a quantified, typical chemical concept, which correlates the ability of chemical species to attract electrons during their contact with other species with measurable quantities such as dissociation energies, dipole moments, ionic radii, ionization potentials, electron affinities and spectroscopic data. It is applied to the description and explanation of chemical polarity, reaction mechanisms, other concepts such as acidity and oxidation, the estimation of types of chemical compounds and periodicity. Although this concept is very successful and widely used, and in (...) spite of the fact that it is still subject to scientific investigations, neither a more than intuitive definition nor a generally accepted, logically clear and standardized quantification model has been developed. In the present work, electronegativity is presented and discussed with respect to its main conceptual and operational continuities and discontinuities. We try to analyze the epistemological status of electronegativity, conceived as a typical notion of chemical sciences. Under ‘epistemological status’ we subsume the issues of its reference, its historical persistence, and the relationship between its measurement and quantification. (shrink)

Immanuel Kant has built up a dualistic epistemology that seems to fit to the peculiarities of chemistry quite well. Friedrich Paneth used Kant’s concept and characterised simple and basic substances which refer to the empirical and to the transcendental world, respectively. This paper takes account of the Kantian influences in Paneth’s philosophy of chemistry, and discusses pertinent topics, like observables, atomism and realism.

The eminent radiochemist Friedrich Paneth (1887–1958) tried to come to terms with the following epistemological problem: On the one hand chemical elements are characterized empirically as indestructible material species, on the other hand they are characterized theoretically as having the same number of protons in the nuclei of their atoms. Paneth used the dualistic Kantian epistemology (using Eduard von Hartmann's interpretation) in order to describe the combination of these two aspects, applying the terms “Grundstoff”, fundamental matter, to the latter and (...) “einfacher Stoff”, simple matter, to the former. The present paper discusses the applicability of Kant's philosophy – in the interpretation of Paneth – to the (modern) philosophy of chemistry. (shrink)

In this short essay I address the central topic of the Centenary Workshop on Acidity, that is the relations of the classical protonist acid–base theory by Brønsted and the electronist approach by Lewis. Emphasis is laid on the empirical background of both approaches and the over-theoretization of chemical phenomena (essentialism) is criticized.

Dies ist eine der wenigen umfassenden Monographien zur Philosophie der großen Naturwissenschaft Chemie auf dem aktuellen Stand der seit etwa drei Jahrzehnten aufblühenden wissenschaftsphilosophischen Teildisziplin. Es wird untersucht, wie die zentralen Aspekte Stofflichkeit, Analyse, Synthese, Kompositionismus, Potentialität, Affinität, Reaktivität, Temporalität, Atomismus, Individuen, Arten, Bindungstheorie, Unterbestimmtheit, und Pluralismus in der Chemie zusammenhängen. Die These wird vertreten, dass es der Chemie keinerlei Abbruch hinsichtlich ihrer wissenschaftlichen Bedeutung tut, sie mit Kant als „systematische" Kunst anzusehen. Vielmehr besteht sogar Anlass, sich mit einer gleichsam (...) „metachemischen" Grundhaltung von den Unzulänglichkeiten herkömmlicher Wissenschaftstheorie zu lösen. Das Buch ist die Bilanz von Bemühungen des Autors in der Chemiephilosophie in den genannten drei Jahrzehnten. (shrink)

Chemistry as the special science of the elements Content Type Journal Article DOI 10.1007/s11016-010-9458-4 Authors Klaus Ruthenberg, Faculty of Science, Coburg University of Applied Sciences, 96406 Coburg, Germany Journal Metascience Online ISSN 1467-9981 Print ISSN 0815-0796.

After a brief biography of Jaap van Brakel we set out his appropriation and use of the distinction between the manifest image and the scientific image of the world. In a certain sense van Brakel gives priority to the manifest image as the ultimate source of meaning in chemical discourses. He does not take sides in the debate about nominal and real essences, twin earths and so, but presents a compromise. As an active practitioner of the chemical arts he emphasises (...) the indispensability of models as a main tool for chemical thinking. We then turn to van Brakel’s interest in forging an intercultural point of view in which philosophy of chemistry plays an important part. (shrink)