The success of a few theories in statistical thermodynamics can be correlated with their selectivity to reality. These are the theories of Boltzmann, Gibbs, and Einstein. The starting point is Carnot’s theory, which defines implicitly the general selection of reality relevant to thermodynamics. The three other theories share this selection, but specify it further in detail. Each of them separates a few main aspects within the scope of the implicit thermodynamic reality. Their success grounds on that selection. (...) Those aspects can be represented by corresponding oppositions. These are: macroscopic – microscopic; elements – states; relational – non-relational; and observable – theoretical. They can be interpreted as axes of independent qualities constituting a common qualitative reference frame shared by those theories. Each of them can be situated in this reference frame occupying a different place. This reference frame can be interpreted as an additional selection of reality within Carnot’s initial selection describable as macroscopic and both observable and theoretical. The deduced reference frame refers implicitly to many scientific theories independent of their subject therefore defining a general and common space or subspace for scientific theories (not for all). The immediate conclusion is: The examples of a few statistical thermodynamic theories demonstrate that the concept of “reality” is changed or generalized, or even exemplified (i.e. “de-generalized”) from a theory to another. Still a few more general suggestions referring the scientific realism debate can be added: One can admit that reality in scientific theories is some partially shared common qualitative space or subspace describable by relevant oppositions and rather independent of their subject quite different in general. Many or maybe all theories can be situated in that space of reality, which should develop adding new dimensions in it for still newer and newer theories. Its division of independent subspaces can represent the many-realities conception. The subject of a theory determines some relevant subspace of reality. This represents a selection within reality, relevant to the theory in question. The success of that theory correlates essentially with the selection within reality, relevant to its subject. (shrink)

The success of a few theories in statistical thermodynamics can be correlated with their selectivity to reality. These are the theories of Boltzmann, Gibbs, end Einstein. The starting point is Carnot’s theory, which defines implicitly the general selection of reality relevant to thermodynamics. The three other theories share this selection, but specify it further in detail. Each of them separates a few main aspects within the scope of the implicit thermodynamic reality. Their success grounds on that selection. (...) Those aspects can be represented by corresponding oppositions. These are: macroscopic – microscopic; elements – states; relational – non-relational; and observable – theoretical. They can be interpreted as axes of independent qualities constituting a common qualitative reference frame shared by those theories. Each of them can be situated in this reference frame occupying a different place. This reference frame can be interpreted as an additional selection of reality within Carnot’s initial selection describable as macroscopic and both observable and theoretical. The deduced reference frame refers implicitly to many scientific theories independent of their subject therefore defining a general and common space or subspace for scientific theories (not for all). The immediate conclusion is: The examples of a few statistical thermodynamic theories demonstrate that the concept of “reality” is changed or generalized, or even exemplified (i.e. “de-generalized”) from a theory to another. Still a few more general suggestions referring the scientific realism debate can be added: One can admit that reality in scientific theories is some partially shared common qualitative space or subspace describable by relevant oppositions and rather independent of their subject quite different in general. Many or maybe all theories can be situated in that space of reality, which should develop adding new dimensions in it for still newer and newer theories. Its division of independent subspaces can represent the many-realities conception. The subject of a theory determines some relevant subspace of reality. This represents a selection within reality, relevant to the theory in question. The success of that theory correlates essentially with the selection within reality, relevant to its subject. (shrink)

The emergent properties are properties referring to a system as a whole, but they do not make sense to its elements or parts being small enough. Furthermore certain emergent properties are reducible to those of elements or relevant parts often. The paper means the special case where the description of the system by means of its emergent properties is much simpler than that of its relevant elements or parts. The concept is investigated by a (...) case study based on statistic thermodynamics, general relativity, and quantum mechanics. (shrink)

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann’s analysis, the essence of which I shall review here, is basically correct. The most famous criticisms of Boltzmann’s later work on the subject have little merit. Most twentieth century innovations – such as the identification of the state of a physical system with a probability distribution on its phase (...) space, of its thermodynamic entropy with the Gibbs entropy of , and the invocation of the notions of ergodicity and mixing for the justification of the foundations of statistical mechanics – are thoroughly misguided. (shrink)

The recent surge of interest in the origin of the temporal asymmetry of thermodynamical systems (including the accessible part of the universe itself) has put forward two possible explanatory approaches to this age-old problem. Hereby we show that there is a third possible alternative, based on the generalization of the classical (“Boltzmann–Schuetz”) anthropic fluctuation picture of the origin of the perceived entropy gradient. This alternative (which we dub the Acausal-Anthropic approach) is based on accepting Boltzmann's statistical measure at its (...) face value, and accomodating it within the quantum cosmological concept of the multiverse. We argue that conventional objections raised against the Boltzmann–Schuetz view are less forceful and serious than it is usually assumed. A fortiori, they are incapable of rendering the generalized theory untenable. On the contrary, this analysis highlights some of the other advantages of the multiverse approach to the thermodynamical arrow of time. (shrink)

I give a fairly systematic and thorough presentation of the case for regarding black holes as thermodynamic systems in the fullest sense, aimed at students and non-specialists and not presuming advanced knowledge of quantum gravity. I pay particular attention to the availability in classical black hole thermodynamics of a well-defined notion of adiabatic intervention; the power of the membrane paradigm to make black hole thermodynamics precise and to extend it to local-equilibrium contexts; the central role of Hawking radiation (...) in permitting black holes to be in thermal contact with one another; the wide range of routes by which Hawking radiation can be derived and its back-reaction on the black hole calculated; the interpretation of Hawking radiation close to the black hole as a gravitationally bound thermal atmosphere. In an appendix I discuss recent criticisms of black hole thermodynamics by Dougherty and Callender. This paper confines its attention to the thermodynamics of black holes; a sequel will consider their statistical mechanics. (shrink)

This chapter will review selected aspects of the terrain of discussions about probabilities in statistical mechanics (with no pretensions to exhaustiveness, though the major issues will be touched upon), and will argue for a number of claims. None of the claims to be defended is entirely original, but all deserve emphasis. The first, and least controversial, is that probabilistic notions are needed to make sense of statistical mechanics. The reason for this is the same reason that convinced Maxwell, (...) Gibbs, and Boltzmann that probabilities would be needed, namely, that the second law of thermodynamics, which in its original formulation says that certain processes are impossible, must, on the kinetic theory, be replaced by a weaker formulation according to which what the original version deems impossible is merely improbable. Second is that we ought not take the standard measures invoked in equilibrium statistical mechanics as giving, in any sense, the correct probabilities about microstates of the system. We can settle for a much weaker claim: that the probabilities for outcomes of experiments yielded by the standard distributions are effectively the same as those yielded by any distribution that we should take as a representing probabilities over microstates. Lastly, (and most controversially): in asking about the status of probabilities in statistical mechanics, the familiar dichotomy between epistemic probabilities (credences, or degrees of belief) and ontic (physical) probabilities is insufficient; the concept of probability that is best suited to the needs of statistical mechanics is one that combines epistemic and physical considerations. (shrink)

A major part of Einstein’s 1905 light quantum paper is devoted to arguing that high frequency heat radiation bears the characteristic signature of a microscopic energy distribution of independent, spatially localized components. The content of his light quantum proposal was precarious in that it contradicted the great achievement of nineteenth century physics, the wave theory of light and its accommodation in electrodynamics. However the methods used to arrive at it were both secure and familiar to Einstein in 1905. A mainstay (...) of Einstein’s research in statistical physics, extending to his earliest publications of 1901 and 1902, had been the inferring of the microscopic constitution of systems from their macroscopic properties. In his statistical work of 1905, Einstein dealt with several thermal systems consisting of many, independent, spatially localized components. They were the dilute sugar solutions of his doctoral dissertation and suspended particles of his Brownian motion paper. (shrink)

Emergence is often described as the idea that the whole is greater than the sum of the parts: interactions among the components of a system lead to distinctive novel properties. It has been invoked to describe the flocking of birds, the phases of matter and human consciousness, along with many other phenomena. Since the nineteenth century, the notion of emergence has been widely applied in philosophy, particularly in contemporary philosophy of mind, philosophy of science and metaphysics. It has more (...) recently become central to scientists' understanding of phenomena across physics, chemistry, complexity and systems theory, biology and the social sciences. The Routledge Handbook of Emergence is an outstanding reference source and exploration of the concept of emergence, and is the first collection of its kind. Thirty-two chapters by an international team of contributors are organised into four parts: Foundations of emergence Emergence and mind Emergence and physics Emergence and the special sciences Within these sections important topics and problems in emergence are explained, including the British Emergentists; weak vs. strong emergence; emergence and downward causation; dependence, complexity and mechanisms; mental causation, consciousness and dualism; quantum mechanics, soft matter and chemistry; and evolution, cognitive science and social sciences. Essential reading for students and researchers in philosophy of mind, philosophy of science and metaphysics, The Routledge Handbook of Emergence will also be of interest to those studying foundational issues in biology, chemistry, physics and psychology. (shrink)

Roughly speaking, classical statistical physics is the branch of theoretical physics that aims to account for the thermal behaviour of macroscopic bodies in terms of a classical mechanical model of their microscopic constituents, with the help of probabilistic assumptions. In the last century and a half, a fair number of approaches have been developed to meet this aim. This study of their foundations assesses their coherence and analyzes the motivations for their basic assumptions, and the interpretations of their central (...) concepts. The most outstanding foundational problems are the explanation of time-asymmetry in thermal behaviour, the relative autonomy of thermal phenomena from their microscopic underpinning, and the meaning of probability. A more or less historic survey is given of the work of Maxwell, Boltzmann and Gibbs in statistical physics, and the problems and objections to which their work gave rise. Next, we review some modern approaches to (i) equilibrium statistical mechanics, such as ergodic theory and the theory of the thermodynamic limit; and to (ii) non-equilibrium statistical mechanics as provided by Lanford's work on the Boltzmann equation, the so-called Bogolyubov-Born-Green-Kirkwood-Yvon approach, and stochastic approaches such as `coarse-graining' and the `open systems' approach. In all cases, we focus on the subtle interplay between probabilistic assumptions, dynamical assumptions, initial conditions and other ingredients used in these approaches. (shrink)

Part I of the present work outlined the rigorous application of information theory to a quantum mechanical system in a thermodynamic equilibrium state. The general formula developed there for the best-guess density operator $\hat \rho$ was indeterminate because it involved in an essential way an unspecified prior probability distribution over the continuumD H of strong equilibrium density operators. In Part II mathematical evaluation of $\hat \rho$ is completed after an epistemological analysis which leads first to the discretization ofD H and (...) then to the adoption of a suitable indifference axiom to delimit the set of admissible prior distributions. Finally, quantal formulas for information-theoretic and thermodynamic entropies are contrasted, and the entire work is summarized. (shrink)

I present in detail the case for regarding black hole thermodynamics as having a statistical-mechanical explanation in exact parallel with the statistical-mechanical explanation believed to underly the thermodynamics of other systems. I focus on three lines of argument: zero-loop and one-loop calculations in quantum general relativity understood as a quantum field theory, using the path-integral formalism; calculations in string theory of the leading-order terms, higher-derivative corrections, and quantum corrections, in the black hole entropy formula for extremal (...) and near-extremal black holes; recovery of the qualitative and quantitative structure of black hole statistical mechanics via the AdS/CFT correspondence. In each case I briefly review the content of, and arguments for, the form of quantum gravity being used at a introductory level: the paper is aimed at students and non-specialists and does not presume advanced knowledge of quantum gravity.. My conclusion is that the evidence for black hole statistical mechanics is as solid as we could reasonably expect it to be in the absence of a directly-empirically-verified theory of quantum gravity. (shrink)

The present article provides a mereological analysis of Euclid’s planar geometry as presented in the first two books of his Elements. As a standard of comparison, a brief survey of the basic concepts of planar geometry formulated in a set-theoretic framework is given in Section 2. Section 3.2, then, develops the theories of incidence and order using a blend of mereology and convex geometry. Section 3.3 explains Euclid’s “megethology”, i.e., his theory of magnitudes. In Euclid’s system of geometry, megethology (...) takes over the role played by the theory of congruence in modern accounts of geometry. Mereology and megethology are connected by Euclid’s Axiom 5: “The whole is greater than the part.” Section 4 compares Euclid’s theory of polygonal area, based on his “Whole-Greater-Than-Part” principle, to the account provided by Hilbert in his Grundlagen der Geometrie. An hypothesis is set forth why modern treatments of geometry abandon Euclid’s Axiom 5. Finally, in Section 5, the adequacy of atomistic mereology as a framework for a formal reconstruction of Euclid’s system of geometry is discussed. (shrink)

This work assembles some basic theoretical elements on thermal equilibrium, stability conditions, and fluctuation theory in self-gravitating systems illustrated with a few examples. Thermodynamics deals with states that have settled down after sufficient time has gone by. Time dependent phenomena are beyond the scope of this paper. While thermodynamics is firmly rooted in statistical physics, equilibrium configurations, stability criteria and the destabilizing effect of fluctuations are all expressed in terms of thermodynamic functions. The work is not (...) a review paper but a pedagogical introduction which may interest theoreticians in astronomy and astrophysicists. It contains sufficient mathematical details for the reader to redo all calculations. References are only to seminal works or readable reviews. Delicate mathematical problems are mentioned but are not discussed in detail. (shrink)

Until the late 19th century scientists almost always assumed that the world could be described as a rule-based and hence deterministic system or as a set of such systems. The assumption is maintained in many 20th century theories although it has also been doubted because of the breakthrough of statistical theories in thermodynamics (Boltzmann and Gibbs) and other fields, unsolved questions in quantum mechanics as well as several theories forwarded within the social sciences. Until recently it has furthermore (...) been assumed that a rule-based and deterministic system was also predictable if only the rules were known, but this assumption has now been undermined by modern chaos-theory describing rule-based and deterministic, but unpredictable systems, while catastrophe-theory delivers a set of types describing various kinds of instability and conditions for the stability of a given system. Hence the main trait in the theoretical development in the 20th-century science can be described as a basic modification and limitation of some of the fundamental and strong assumptions forwarded in the previous epochs of modern science. Ironically, the very same process has been a process in which the human capacity to intervene in nature has expanded dramatically and mainly with the help of the very same theories, and not least because they allow nature to be described and made manipulable on a lower level and a more fine-grained scale. While the overall theoretical consistency between the various theories has gone, the reach of human intervention in nature has increased based on quite new dimensions whether in the area of physics (e.g.: energy technologies, chemical technologies, nanotechnologies etc.) or biology (ge¬netic manipulation) or in the area of psychology, sociology and culture (artificial simulations of mental processes, new means of communication, implying changes in the social infrastructure and cultural behaviour etc.). While some of these changes and new conditions can be reflected from within the conceptual framework of rule-based systems, albeit more complex than formerly recognized, others seem to give rise to the question of whether there are »systems« and relations between different systems in the world which are not rule-based? For instance, it seems to be obvious that the notion of instability represents a major conceptual break with former theories of rule-based systems, as the stability of the latter is an axiomatically given property implied in the very notion of rule-based systems, while instability can only be the result of external influence which should be explained as the result of another rule-based sy¬stem. While there are no difficulties implied concerning the stability of rule-based systems, the notion of unstable states of a system raises the question of how there can be a system at all if there are no invariant stabilising principles? This is the first question which I will address. And I shall do so by taking two examples of such systems as my point of departure. The first example will be the computer and the second will be ordinary language. In both cases I will argue that the stability of these systems (which are both defined by the existence/presence of human intentions) are provided by the help of - differently organised - redundancy functions which both allow the maintenance of systems in unstable macro-states, suspension of previous rules, underdetermination and overdetermination and generation/emergence/creation of new rules more or less independent of previous rules by the help of optional recursions to the permanently accessible underlying levels as for instance the level of binary representation in computers. Since the notion of redundancy is both controversial as such and often avoided, the concept is discussed (as defined in Claude Shannon's mathematical theory of information and in the semiotic framework of J. J. Greimas) and leading to a more general definition in which the redundancy functions serve to overcome noisy conditions, but at the cost of rule-based stability, determination, and predictability. A second question will be how the notion of rule-generating systems relates to the notion of anticipatory systems and it will be argued that rule-generating systems share some features with an¬ticipatory systems and that the former from a certain viewpoint can be seen as a subclass of the latter, although anticipative features are not necessarily a part of the definition of rule-generating systems. On the other hand, it will be discussed whether anticipatory systems which are not rule-generating systems can exist and it will be argued that the capacity to anticipate is strongly limited if it is not part of a rule-generating system. Therefore, it is concluded that the most powerful anticipatory systems need to be rule-generating systems. (shrink)

Ludwig Boltzmann is one of the foremost responsible for the development of modern atomism in thermodynamics. His proposition was revolutionary not only because it brought a new vision for Thermodynamics, merging a statistical approach with Newtonian physics, but also because he produced an entirely new perspective on the way of thinking about and describing physical phenomena. Boltzmann dared to flirt with constructivism and realism simultaneously, by hypothesizing the reality of atoms and claiming an inherent probabilistic nature related (...) to many particles systems. Boltzmann faced criticism from the positivists, who rejected the hypothesis of the atom as a matter of principle, and also from physicists, who rejected the idea of a classical bounded system that does not follow deterministic mechanical laws. We consider that Boltzmann thermodynamics has emerged as a systemic theory that deals with macroscopic bodies using collective variables; it was reformulated to a kinetic theory of gases, and subsequently to statistical mechanics. From the theoretical physical point of view, Boltzmann advocates an approach to thermodynamics based on mechanics and was one of the founders of statistical mechanics, together with ideas by Maxwell, Clausius and Gibbs. Subsequently, statistical mechanics has also influenced the development of quantum mechanics and information theory. Using an evolutionary epistemological perspective as a metaphor to describe the physical entities claimed in Boltzmann propositions, we interpret his work as a selected theory that gained attributes of reality and “survived” during a scientific-contextual competition to be more adapted, in the sense that it was able to better explain physical phenomena, and also generated “descendants”. (shrink)

Thermodynamics is the foundation of many of the topics of interest in the religion‐science dialogue. Here a nonmathematical outline of the principles of thermodynamics is presented, providing a historical and conceptually understandable development that can serve teachers from disciplines other than physics. The contributions of Gibbs to both classical and rational thermodynamics, emphasizing the importance of the ensemble in statistical mechanics, are discussed. The seminal ideas of Boltzmann on statistical mechanics are contrasted to those of (...) Gibbs in a discussion of the microscopic interpretation of the second law. The role of information theory is discussed, and the modern ideas of Prigogine and nonequilibrium are outlined in some detail with further reference to the second law. Implications for our interaction with God are considered. (shrink)

Gases reach equilibrium when left to themselves. Why do they behave in this way? The canonical answer to this question, originally proffered by Boltzmann, is that the systems have to be ergodic. This answer has been criticised on different grounds and is now widely regarded as flawed. In this paper we argue that some of the main arguments against Boltzmann's answer, in particular, arguments based on the KAM-theorem and the Markus-Meyer theorem, are beside the point. We then argue that something (...) close to Boltzmann's original proposal is true for gases: gases behave thermodynamic-like if they are epsilon-ergodic, i.e., ergodic on the entire accessible phase space except for a small region of measure epsilon. This answer is promising because there are good reasons to believe that relevant systems in statistical mechanics are epsilon-ergodic. (shrink)

In this paper I first argue that the objection which is most commonly levelled against the coarse-graining approach-viz. that it introduces an element of subjectivity into what ought to be a purely objective formalism-is ultimately unfounded. I then proceed to argue that two different objections to the coarse-graining approach indicate that it is an inadequate approach to statistical mechanics. The first objection is based on the fact that the appeal to appearances by the coarse-graining approach fails to justify the (...) coarse-graining strategy of ignoring the physical differences between so-called quasi-equilibrium distributions and equilibrium distributions. The second objection is centred on the notion of a coarse-grained entropy. I will argue that the required increase in the coarse-grained entropy is obtained by disregarding the dynamical constraints on the system. This undermines the very task statistical mechanics has set out to accomplish, viz. to provide a microdynamical underpinning of thermodynamics. (shrink)

The manifesto presented in Philip Kitcher's exhaustive appraisal of contemporary American education—and the case for its potential reform—is so wide-ranging that it is not possible to do justice to its every component. Instead, I will speak to one of its parts in an attempt to recognize what I take to be the value of the whole. My aim is to address the section on the role of the arts in formal education, and the nature of aesthetic experience within that, (...) to test whether we can take the arts from their current state of being subject to Adam Smith's model of market utility, to being appreciated for their necessary and organic vitality. Kitcher provides strong arguments for exposure to the arts as leading to invaluable aesthetic experiences for young people. By extension—and at times by contrast—I will explore the possibility that the ‘aesthetic’ in aesthetic education does not just come into force with the student's encounter with art works or creative activity in the classroom, but should be integral also to the development of a particular sensibility amongst educators (i.e. the aesthetic education of the educators) for the shape and form of a ‘good’ education, according to its context and circumstance. It is through this sensibility that we might rediscover the necessity of the arts in schools at a time when their importance has been significantly devalued. (shrink)

A new axiomatic treatment of equilibrium thermodynamics—thermostatics—is presented. The equilibrium states of a thermal system are assumed to be represented by a differentiable manifold of dimensionn + 1 (n finite). The empirical temperature is defined by the notion of thermal equilibrium. Empirical entropy is shown to exist for all systems with the property that the total work delivered along closed adiabats is zero. Absolute entropy and temperature follow from the additivity of heat and energy for two separate systems in (...) thermal equilibrium considered as a whole. The absolute temperature is defined up to a multiplicative constant. The exterior differentiable calculus of Cartan is introduced and in a subsequent paper its use for the derivation of standard results in thermostatics will be explained. (shrink)

After the birth of thermodynamics’ second principle—outlined in Carnot's Réflexions sur la puissance motrice du feu —several studies provided new arguments in the field. Mainly, they concerned the thermodynamics’ first principle—including energy conceptualisation—, the analytical aspects of the heat propagation, the statistical aspects of the mechanical theory of heat. In other words, the second half of nineteenth century was marked by an intense interdisciplinary research activity between physics and chemistry: new disciplines applied to the heat developed in (...) the form of analytical, mechanical and statistical theories. Inside all these theories, entropy—the brand-new function that Clausius coined in his Mechanical theory of heat—started to play a central epistemic role. In the present paper, we analyse some steps of the historical process of conceptualisation of such function from 1850 to 1902. Particularly, we retrace the historical–foundational path that—starting from Clausius’ Second Law—lead Boltzmann and Gibbs to their distinguished formulations of statistical entropy. As usual, our research has been unrolled through the analyses of primary sources and by leaning on critical readings of the secondary literature. As for the methodological approach, text analysis of historical documents constituted our privileged modus operandi. This paper is the expression of a collaborative historical research program focused on the thermodynamic foundations of physics–chemistry relationship; early results have already been published by the same authors upon the concepts of reversibility––and––thermal equilibrium. (shrink)

In a previous work (M. Campisi. Stud. Hist. Phil. M. P. 36 (2005) 275-290) we have addressed the mechanical foundations of equilibrium thermodynamics on the basis of the Generalized Helmholtz Theorem. It was found that the volume entropy provides a good mechanical analogue of thermodynamic entropy because it satisfies the heat theorem and it is an adiabatic invariant. This property explains the ``equal'' sign in Clausius principle ($S_f \geq S_i$) in a purely mechanical way and suggests that the volume (...) entropy might explain the ``larger than'' sign (i.e. the Law of Entropy Increase) if non adiabatic transformations were considered. Based on the principles of microscopic (quantum or classical) mechanics here we prove that, provided the initial equilibrium satisfy the natural condition of decreasing ordering of probabilities, the expectation value of the volume entropy cannot decrease for arbitrary transformations performed by some external sources of work on a insulated system. This can be regarded as a rigorous quantum mechanical proof of the Second Law. We discuss how this result relates to the Minimal Work Principle and improves over previous attempts. The natural evolution of entropy is towards larger values because the natural state of matter is at positive temperature. Actually the Law of Entropy Decrease holds in artificially prepared negative temperature systems. (shrink)

Or better: time asymmetry in thermodynamics. Better still: time asymmetry in thermodynamic phenomena. “Time in thermodynamics” misleadingly suggests that thermodynamics will tell us about the fundamental nature of time. But we don’t think that thermodynamics is a fundamental theory. It is a theory of macroscopic behavior, often called a “phenomenological science.” And to the extent that physics can tell us about the fundamental features of the world, including such things as the nature of time, we (...) generally think that only fundamental physics can. On its own, a science like thermodynamics won’t be able to tell us about time per se. But the theory will have much to say about everyday processes that occur in time; and in particular, the apparent asymmetry of those processes. The pressing question of time in the context of thermodynamics is about the asymmetry of things in time, not the asymmetry of time, to paraphrase Price ( , ). I use the title anyway, to underscore what is, to my mind, the centrality of thermodynamics to any discussion of the nature of time and our experience in it. The two issues—the temporal features of processes in time, and the intrinsic structure of time itself—are related. Indeed, it is in part this relation that makes the question of time asymmetry in thermodynamics so interesting. This, plus the fact that thermodynamics describes a surprisingly wide range of our ordinary experience. We’ll return to this. First, we need to get the question of time asymmetry in thermodynamics out on the table. (shrink)

In previous publications we have criticized the usual application of information theory to quantal situations and proposed a new version of information-theoretic quantum statistics. This paper is the first in a two-part series in which our new approach is applied to the fundamental problem of thermodynamic equilibrium. Part I deals in particular with informational definitions of equilibrium and the identification of thermodynamic analogs in our modified quantum statistics formalism.

The theory of beauty has always rested on the representation of the infinite, understood in its finite expression and perceptible through the senses. The relationship of beauty to truth, of art to science, is inevitably modified with the new way of treating the infinite in the modern conception of the world. Non-classical science works with the notions of “infinitely large” and “infinitely small,” modifying their meanings in terms of experimental observations. We put these words in quotation marks because the Whole (...) may be considered as finite or infinite according to the angle from which it is viewed: the “infinitely small” only becomes so in determined circumstances, for example, when we consider the extended and discrete elements of space and time in a macroscopic approximation, as infinitely small elements of perpetual motion. Modern science studies these two poles of being—the Whole and its parts—in their interaction, admitting the dependence of macroscopic and even cosmic processes with regard to the processes being created in infinitely small spheres (or, according to another interpretation, finite but extremely small). However, as characteristic of our time as these concepts are—most often hypothetical—they nonetheless express a very old historical tradition that contemporary retrospection, turned toward classical science and the past of science in general, allows us to discern very clearly. All the culture of the past was dominated by the principle of the authority of the Whole over its parts. In peripatetic cosmology and physics, individual processes depended on the cosmic harmony of the center and frontiers of the universe, on the spheres and places toward which bodies tend. This authority of the general law, of universal harmony, of the system hinging on individual processes, is confirmed in Aristotle's Physics, but not only there: we find it in almost all the thinkers of antiquity. On the plane of general logic, it received expression in the Hegelian concept of the true infinite, a concept constituting to a high degree the philosophical equivalent of classical science. In Hegel's time, this last was already drawing away somewhat from the idea of an absolute and strict subordination of elementary processes to integrating systems and general laws, laws being realized through the probability of microprocesses, thus statistical laws, and whose exact application ignored individual acts, for example, the mechanism of molecules in thermodynamics. The statistical theory of heat has rendered continual a discrete microcosm—for the movement of individual molecules it substituted the average speed of the molecules—and continual laws became supreme points determining macroscopic processes. These laws had a differential nature. In other words, they prescribed the defined relationships between the infinitely small increases in size. Also, the schema of the classic law consisted in defining infinitely small processes by an infinitely large integral legality because of the number of processes. The infinitely true of Hegel is the actual infinite being realized in each of its finite elements; it is the subjection of the finite element to the infinite. (shrink)

Based on the property of extensivity , we derive in a mathematically consistent manner the explicit expressions of the chemical potential μμ and the Clausius entropy S for the case of monoatomic ideal gases in open systems within phenomenological thermodynamics. Neither information theoretic nor quantum mechanical statistical concepts are invoked in this derivation. Considering a specific expression of the constant term of S, the derived entropy coincides with the Sackur–Tetrode entropy in the thermodynamic limit. We demonstrate, however, (...) that the former limit is not contained in the classical thermodynamic relations, implying that the usual resolutions of Gibbs paradox do not succeed in bridging the gap between the thermodynamics and statistical mechanics. We finally consider the volume of the phase space as an entropic measure, albeit, without invoking the thermodynamic limit to investigate its relation to the thermodynamic equation of state and observables. (shrink)

The search for the statistical mechanical underpinning of thermodynamic irreversibility has so far focussed on the spontaneous approach to equilibrium. But this is the search for the underpinning of what Brown and Uffink have dubbed the ‘minus first law’ of thermodynamics. In contrast, the second law tells us that certain interventions on equilibrium states render the initial state ‘irrecoverable’. In this article, I discuss the unusual nature of processes in thermodynamics, and the type of irreversibility that the (...) second law embodies. I then search for the microscopic underpinning or statistical mechanical ‘reductive basis’ of the second law of thermodynamics by taking a functionalist strategy. First, I outline the functional role of the thermodynamic entropy: for a thermally isolated system, the thermodynamic entropy is constant in quasi-static processes, but increasing in non-quasi-static processes. I then search for the statistical mechanical quantity that plays this role—rather than the role of the traditional ‘holy grail’ as described by Callender. I argue that in statistical mechanics, the Gibbs entropy plays this role. (shrink)

In this chapter, I urge a fresh look at the problem of explaining equilibration. The process of equilibration, I argue, is best seen not as part of the subject matter of thermodynamics, but as a presupposition of thermodynamics. Further, the relevant tension between the macroscopic phenomena of equilibration and the underlying microdynamics lies not in a tension between time-reversal invariance of the microdynamics and the temporal asymmetry of equilibration, but in a tension between preservation of distinguishability of states (...) at the level of microphysics and the continual effacing of the past at the macroscopic level. This suggests an open systems approach, where the puzzling question is not the erasure of the past, but the question of how reliable prediction, given only macroscopic data, is ever possible at all. I suggest that the answer lies in an approach that has not been afforded sufficient attention in the philosophical literature, namely, one based on the temporal asymmetry of causal explanation. (shrink)

It has become something of a dogma in the philosophy of science that modern cosmology has completed Boltzmann's program for explaining the statistical validity of the Second Law of thermodynamics by providing the low entropy initial state needed to ground the asymmetry in entropic behavior that underwrites our inference about the past. This dogma is challenged on several grounds. In particular, it is argued that it is likely that the Boltzmann entropy of the initial state of the universe (...) is an ill-defined or severely hobbled concept. It is also argued that even if the entropy of the initial state of the universe had a well-defined, low value, this would not suffice to explain why thermodynamics works as well as it does for the kinds of systems we care about. Because the role of Boltzmann entropy in our inferences to the past has been vastly overrated, the failure of the Boltzmann program does not pose a serious problem for our knowledge of the past. But it does call a different explanation of why thermodynamics works as well as it does. A suggestion is offered for a different approach. (shrink)

The aim of this article is to analyse the relation between the second law of thermodynamics and the so-called arrow of time. For this purpose, a number of different aspects in this arrow of time are distinguished, in particular those of time-reversal (non-)invariance and of (ir)reversibility. Next I review versions of the second law in the work of Carnot, Clausius, Kelvin, Planck, Gibbs, Caratheodory and Lieb and Yngvason, and investigate their connection with these aspects of the arrow of time. (...) It is shown that this connection varies a great deal along with these formulations of the second law. According to the famous formulation by Planck, the second law expresses the irreversibility of natural processes. But in many other formulations irreversibility or even time-reversal non-invariance plays no role. I therefore argue for the view that the second law has nothing to do with the arrow of time. (shrink)

Since the late nineteenth century, physics has been puzzled by the time-asymmetry of thermodynamic phenomena in the light of the apparent T-symmetry of the underlying laws of mechanics. However, a compelling solution to this puzzle has proved elusive. In part, I argue, this can be attributed to a failure to distinguish two conceptions of the problem. According to one, the main focus of our attention is a time-asymmetric lawlike generalisation. According to the other, it is a particular fact about the (...) early universe. This paper aims (i) to distinguish these two different conceptions of the time-asymmetric explanandum in thermodynamics; (ii) to argue in favour of the latter; and (iii) to show that whichever we choose, our rational expectations about the thermodynamic behaviour of the future must depend on what we know about the past: contrary to the common view, statistical arguments alone do not give us good reason to expect that entropy will always continue to increase. (shrink)

Consider a gas that is adiabatically isolated from its environment and confined to the left half of a container. Then remove the wall separating the two parts. The gas will immediately start spreading and soon be evenly distributed over the entire available space. The gas has approached equilibrium. Thermodynamics (TD) characterizes this process in terms of an increase of thermodynamic entropy, which attains its maximum value at equilibrium. The second law of thermodynamics captures the irreversibility of this (...) process by positing that in an isolated system such as the gas entropy cannot decrease. The aim of statistical mechanics (SM) is to explain the behavior of the gas and, in particular, its conformity with the second law in terms of the dynamical laws governing the individual molecules of which the gas is made up. In what follows these laws are assumed to be the ones of Hamiltonian classical mechanics. We should not, however, ask for an explanation of the second law literally construed. This law is a universal law and as such cannot be explained by a statistical theory. But this is not a problem because we.. (shrink)

Equilibrium states are used as limit states to define thermodynamically reversible processes. When these processes are implemented in statistical physics, these limit states become unstable and can change with time, due to thermal fluctuations. For macroscopic systems, the changes are insignificant on ordinary time scales and what little there is can be suppressed by macroscopically negligible, entropy-creating dissipation. For systems of molecular sizes, the changes are large on short time scales and can only sometimes be suppressed with significant entropy-creating (...) dissipation. As a result, at molecular scales, thermodynamically reversible processes are impossible in principle, even as approximations, when we account for all sources of dissipation. (shrink)

Thermodynamic macro variables, such as the temperature or volume macro variable, can take on a continuum of allowable values, called thermodynamic macro values. Although referring to the same macro phenomena, the macro variables of Boltzmannian Statistical Mechanics (BSM) differ from thermodynamic macro variables in an important respect: within the framework of BSM the evolution of macro values of systems with finite available phase space is invariably modelled as discontinuous, due to the method of partitioning phase space into macro regions (...) with sharp, fixed boundaries. Conceptually, this is at odds with the continuous evolution of macro values as described by thermodynamics, as well as with the continuous evolution of the micro state assumed in BSM. This discrepancy I call the discontinuity problem. I show how it arises from BSM’s framework and demonstrate its consequences, in particular for the foundational project of reducing thermodynamics to BSM: thermodynamic macro values are shown to not supervene on the corresponding BSM macro values. With supervenience being a conditio sine qua non for the kind of reduction envisaged by the foundational project, the latter is in jeopardy. (shrink)

Of all global problems world population growth is the most significant. The growth of the number of people expresses the sum outcome of all economic, social and cultural activities that comprise human history. Demographic data in a concise and quantitative way describe this process in the past and present. By applying the concepts of nonlinear dynamics and synergetics, it is possible to work out a mathematical model for a phenomenological description of the global demographic process and project its trends (...) into the future. Assuming self-similarity as the dynamic principle of development, growth can be described over practically the whole of human history, with a growth rate proportional to the square of the number of people. This is due to a collective interaction, responsible for the growth of human numbers, as the result of the informational nature of development. The large parameter of the theory and the effective size of a coherent population group is of the order of 105. As the microscopic parameter of the phenomenology, the human life span is introduced into the theory. Estimates of the beginning of human development 4-5 million years ago and of the total number of people who have ever lived since then ≈ 100 billion are made. In the framework of the model, large scale cycles defined by history and anthropology are shown to follow an exponential pattern of growth, culminating in the demographic transition, a veritable revolution when population growth is to stabilize at 10 to 12 billion. (shrink)

Interpreting Figurative Meaning critically evaluates the recent empirical work from psycholinguistics and neuroscience examining the successes and difficulties associated with interpreting figurative language. There is now a huge, often contradictory literature on how people understand figures of speech. Gibbs and Colston argue that there may not be a single theory or model that adequately explains both the processes and products of figurative meaning experience. Experimental research may ultimately be unable to simply adjudicate between current models in psychology, linguistics and philosophy (...) of how figurative meaning is interpreted. Alternatively, the authors advance a broad theoretical framework, motivated by ideas from 'dynamical systems theory', that describes the multiple, interacting influences which shape people's experiences of figurative meaning in discourse. This book details past research and theory, offers a critical assessment of this work and sets the stage for a new vision of figurative experience in human life. (shrink)

Cognitive theories of metaphor understanding are typically described in terms of the mappings between different kinds of abstract, schematic, disembodied knowledge. My claim in this paper is that part of our ability to make sense of metaphorical language, both individual utterances and extended narratives, resides in the automatic construction of a simulation whereby we imagine performing the bodily actions referred to in the language. Thus, understanding metaphorical expressions like ‘grasp a concept’ or ‘get over’ an emotion involve simulating what it (...) must be like to engage in these specific activities, even though these actions are, strictly speaking, impossible to physically perform. This process of building a simulation, one that is fundamentally embodied in being constrained by past and present bodily experiences, has specific consequences for how verbal metaphors are understood, and how cognitive scientists, more generally, characterize the nature of metaphorical language and thought. (shrink)

Cognitive theories of metaphor understanding are typically described in terms of the mappings between different kinds of abstract, schematic, disembodied knowledge. My claim in this paper is that part of our ability to make sense of metaphorical language, both individual utterances and extended narratives, resides in the automatic construction of a simulation whereby we imagine performing the bodily actions referred to in the language. Thus, understanding metaphorical expressions like ‘grasp a concept’ or ‘get over’ an emotion involve simulating what it (...) must be like to engage in these specific activities, even though these actions are, strictly speaking, impossible to physically perform. This process of building a simulation, one that is fundamentally embodied in being constrained by past and present bodily experiences, has specific consequences for how verbal metaphors are understood, and how cognitive scientists, more generally, characterize the nature of metaphorical language and thought. (shrink)

An intricate, long, and occasionally heated debate surrounds Boltzmann’s H-theorem (1872) and his combinatorial interpretation of the second law (1877). After almost a century of devoted and knowledgeable scholarship, there is still no agreement as to whether Boltzmann changed his view of the second law after Loschmidt’s 1876 reversibility argument or whether he had already been holding a probabilistic conception for some years at that point. In this paper, I argue that there was no abrupt statistical turn. In the (...) first part, I discuss the development of Boltzmann’s research from 1868 to the formulation of the H-theorem. This reconstruction shows that Boltzmann adopted a pluralistic strategy based on the interplay between a kinetic and a combinatorial approach. Moreover, it shows that the extensive use of asymptotic conditions allowed Boltzmann to bracket the problem of exceptions. In the second part I suggest that both Loschmidt’s challenge and Boltzmann’s response to it did not concern the H-theorem. The close relation between the theorem and the reversibility argument is a consequence of later investigations on the subject. (shrink)

The Gibbs Paradox is essentially a set of open questions as to how sameness of gases or fluids are to be treated in thermodynamics and statistical mechanics. They have a variety of answers, some restricted to quantum theory, some to classical theory. The solution offered here applies to both in equal measure, and is based on the concept of particle indistinguishability. Correctly understood, it is the elimination of sequence position as a labelling device, where sequences enter at the (...) level of the tensor product of one-particle state spaces. In both cases it amounts to passing to the quotient space under permutations. ‘Distinguishability’, in the sense in which it is usually used in classical statistical mechanics, is a mathematically convenient, but physically muddled, fiction. (shrink)

This article considers the Gibbs paradox and its implications for three definitions of entropy in statistical mechanics: the “classical” Boltzmann entropy ; the modified Boltzmann entropy that is usually proposed in response to the paradox ; and a generalized version of the latter. It is argued that notwithstanding a recent suggestion to the contrary, the paradox does imply that SB1 is not a satisfactory definition of entropy; SB2 is undermined by “second-order” versions of the paradox; and SB2G solves the (...) paradox but is not a satisfactory definition of entropy. (shrink)

This article highlights and discusses the Ehrenfests’ use of toy models to explore irreversibility in statistical mechanics. In particular, we explore their urn and P–Q models and highlight that, while the former was primarily used to provide a simple counter-example to Zermelo’s objection to Boltzmann’s statistical mechanical underpinning of the Second Law of Thermodynamics, the latter was intended to highlight the role and importance of the Stoßzahlansatz as a cause of the tendency of systems to exhibit entropy (...) increase. We also explain the sense in which these models are toy models and why agents can use them, as the Ehrenfests’ did, to carry out this important work, despite the fact that they do not represent any real system. (shrink)

We reconsider the thermodynamic derivation by L. Boltzmann of the Stefan law and we generalize it for various different physical systems whose chemical potential vanishes. Being only based on classical arguments, therefore independent of the quantum statistics, this derivation applies as well to the saturated Bose gas in various geometries as to “compensated” Fermi gas near a neutrality point, such as a gas of Weyl Fermions. It unifies in the same framework the thermodynamics of many different bosonic or fermionic (...) non-interacting gases which were until now described in completely different contexts. (shrink)

This thesis describes a method to control rare events in non-equilibrium systems by applying physical forces to those systems but without relying on numerical simulation techniques, such as copying rare events. In order to study this method, the book draws on the mathematical structure of equilibrium statistical mechanics, which connects large deviation functions with experimentally measureable thermodynamic functions. Referring to this specific structure as the "phenomenological structure for the large deviation principle", the author subsequently extends it to time-series (...) statistics that can be used to describe non-equilibrium physics. The book features pedagogical explanations and also shows many open problems to which the proposed method can be applied only to a limited extent. Beyond highlighting these challenging problems as a point of departure, it especially offers an effective means of description for rare events, which could become the next paradigm of non-equilibrium statistical mechanics. (shrink)

The part‐whole and element‐system relations are usually not given a temporal interpretation. Taking a thesis of Father Bochenski as a starting point , the author first gives an adequate temporal interpretation of this thesis. Then, he shows that a divergence arises, in non‐static systems, between the system itself and the mereological sum corresponding to it at a certain instant. Therefore, any reductionism has to confront the generally neglected problem of this divergence. Résumé Les relations partie‐tout et élément‐système ne sont pas (...) habituellement interprétées de manière temporelle lorsqu'elles sont approachées de manière formelle. On prend ici pour point de départ une thèse formulée par le P. Bochenski, "tout élément d'un système est une partie propre de ce système", dont on donne d'abord une interpretation temporelle adéquate. On met ensuite en évidence la divergence, pour les systèmes non statiques, du système et de la somme méréologique qui lui correspond en un instant donné. Le réductionnisme doit done affronter le problème généralement négligé de cette divergence. -/- Zusammenfassung Gewöhnlich werden die Relationen zwischen Teil und Ganzem und zwischen Element und System nicht zeitlich interpretiert, wenn sie formal behandelt werden. Von einer These von P. Bochenski ausgehend versucht man zuerst, dieser These eine angemessene zeitliche Interpretation zu geben. Dann zeigt man, dass es bei nicht‐statischen Systemen eine Divergenz zwischen dem System und der ihm zu einer bestimmten Zeit entsprechenden mereologischen Summe gibt. Das sich daraus für den Reduktionismus ergebende Problem wird meist vernächlassigt. (shrink)

We develop a general covariant categorical modeling theory of natural systems' behavior based on the fundamental functorial processes of representation and localization-globalization. In the second part of this study we analyze the semantic bidirectional process of localization-globalization. The notion of a localization system of a complex information structure bears a dual role: Firstly, it determines the appropriate categorical environment of base reference contexts for considering the operational modeling of a complex system's behavior, and secondly, it specifies the global compatibility conditions (...) of local contextual information. A localization system acts on the global information structure of a complex system, partitions it into sorts, and eventually, forces the consistent sheaf-theoretic fibering of the latter over the base category of commutative reference contexts. In this manner, the sheafification of the Spectrum functor of a complex information structure takes place by imposing on the uniform and homologous fibered structure of elements of the Spectrum presheaf the following two requirements of coherence in relation to the localization-globalization process: [i]. Compatibility of information under restriction from the global to the local level, and [ii]. Compatibility of information under extension from the local to the global level. Correspondingly, the options of local and global receive a concrete mathematical meaning with respect to a suitable notion of topology (categorical Grothendieck topology) defined on the base category of commutative reference contexts. Finally, the accurate functorial process modeling of a complex system's behavior, respecting the processes of representation and localization-globalization, is being effectuated by means of establishing a categorical dual equivalence between the category of complex information structures, and the topes of sheaves over the base category of partial or local information carriers, equipped with the categorical topology of epimorphosis families. (shrink)

There ought to exist a description of quantum field theory which does not depend on an external classical time. To achieve this goal, in a recent paper we have proposed a non-commutative special relativity in which space-time and matter degrees of freedom are treated as classical matrices with arbitrary commutation relations, and a space-time line element is defined using a trace. In the present paper, following the theory of Trace Dynamics, we construct a statistical thermodynamics for the non-commutative (...) special relativity, and show that one arrives at a generalized quantum dynamics in which space and time are non-classical and have an operator status. In a future work, we will show how standard quantum theory on a classical space-time background is recovered from here. (shrink)

Rosensohn’s interpretation rejects the thesis that Peirce had several systems, perhaps as many as four, each of which is responsive to his new discoveries in logic. Against this view Rosensohn traces the development of Peirce’s system as a coherent phenomenological search, shaped by his "lifelong interest in logic, the sciences, ethics, aesthetics and metaphysics", and culminating in his phaneroscopy, the description of the phaneron. Rosensohn’s text consists of two parts. Part I, "The Elements of Phenomenology," consists of (...) three chapters, two of which are devoted to a close investigation of Peirce’s 1967 "A New List of Categories." Part II consists of two long chapters, "Phenomenology and Nature " and "Phaneroscopy: The Description of the Phaneron." The book concludes with a critique of Peirce’s fundamental categories—Firstness, Secondness, Thirdness—as these bear on his own phenomenological project. From the standpoint of Peirce’s phenomenology, "whatever is present to the mind has Firstness, Secondness and Thirdness", but on the ontological level the cosmos’ evolution is viewed by him as linear. In addition to the usual bibliography and index, Rosensohn provides a helpful appendix of six key quotations in which Peirce explains phenomenology and phaneroscopy. This volume is vastly more substantial than its limited number of pages might suggest. The publisher crowds the pages with smallish print, generally exceeding 500 words per page. Rosensohn’s text itself is lucid, beautifully written, and skillfully argued. It represents at once an important contribution to Peirce scholarship and to the phenomenological literature.—B.M. (shrink)

The study of metaphor is now firmly established as a central topic within cognitive science and the humanities. We marvel at the creative dexterity of gifted speakers and writers for their special talents in both thinking about certain ideas in new ways, and communicating these thoughts in vivid, poetic forms. Yet metaphors may not only be special communicative devices, but a fundamental part of everyday cognition in the form of 'conceptual metaphors'. An enormous body of empirical evidence from cognitive linguistics (...) and related disciplines has emerged detailing how conceptual metaphors underlie significant aspects of language, thought, cultural and expressive action. Despite its influence and popularity, there have been major criticisms of conceptual metaphor. This book offers an evaluation of the arguments and empirical evidence for and against conceptual metaphors, much of which scholars on both sides of the wars fail to properly acknowledge. (shrink)